Don't bother with super skill shot (soft plunging and hitting Venom with upper flipper). The 2x bonus from the regular skill shot is better.
Doc Ock multiball is a good time to hit the dangerous "Light Lock" target to light the locks for Black Suit multiball
Complete white spiders and shoot either outer loop to start one of four modes.
After successfully completing a mode the next major shot you make will be tripled for the rest of the ball.
Shoot Doc Ock to start multiball, the number of times is a setting. Safer to back hand this shot from right flipper.
If you drain out of Battle Royale with the Royale Jackpot lit, shooting it will award it and restart the Multiball in a 2-ball format.
Finishing all four battles once lights an extra ball, twice lights Battle Royale, and three times is a prerequisite for Super Hero.
After completing white spiders the next shot hit (loops, ramps or Doc Ock) will double the value of that shot for remainder of ball.
Stack white spider doubler with multiball to increase jackpots.
To light Extra Ball, defeat all four villains once. Extra Ball award can be worth 5 Million points in tournament play.